Enzyme-Based/ Biochemical Electrode:
Enzyme
electrodes are operated based on the principle that an enzyme reacts with a
specific substance, and the product of this reaction is detected by a true
ion-selective electrode.
The enzyme is mobilized at the surface of the electrode.
Enzyme electrodes definitely are not true
ion-selective electrodes but usually are considered within the ion-specific
electrode topic.
All these reactions occur inside a special membrane
that covers the true ion-selective electrode, which is why enzyme electrodes
sometimes are considered ion-selective. An example is glucose-selective electrodes.
Glucose electrodes are described for the specific and sensitive determination
of glucose in the blood. The probes are based on the conversion of B-D-glucose by glucose oxidase chemically deposited to the surface of a Platinum electrode.
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