Wavelength Selectors Use in Spectrophotometer| Monochromators

 Monochromator

A device used to produce light of a single wavelength is called a monochromator.

There are two types of monochromators given below:

Prism Monochromator

Light from the radiation source is passed through the collimator. Collimeter is a device used to get a single beam. It makes narrow waves or beams align in a specific direction.

A triangle has a refracting surface that separates white light into a spectrum of seven colors. It is made up of glass.

The beam of light is passed through the prism. The prism resolves the beam of light into different wavelengths. The longer the wavelengths, the more the bend of wavelength will occur.

A wavelength selector or filter selects a specific wavelength, which is then passed through the exit slit. An exit slit is used to get a narrow beam of light.

Transmission grating Monochromators

A diffraction grating is made up of transparent glass. It consists of a series of parallel grooves on a reflecting surface as shown in the figure below.

 Each groove is working as a small separate mirror from which reflected light interacts and interference occurs.

The most commonly used numbers of grooves are 300-2000 per millimeter. The numbers of grooves are 1200-14000 per millimeter are also available.

Both types of interference can occur, constructive and destructive interference. We can calculate it by the following formula:

d (sin i +sin r) = m Æ›

Where m is the positive integer, d is the path difference; Æ› is the wavelength of light, Sin i is the angle of incidence, and Sin r is the angle of refraction.

For constructive interference, path length can be calculated as dsinθ=m ƛ

For destructive interference, path length can be calculated as dsinθ= (n+0.5) ƛ

This phenomenon is used for UV-visible or near Infrared spectroscopy.

Advantages of Transmission Grating over Prism Monochromator

Transmission grating monochromator

Prism monochromator

Better resolution and energy. 

Temperature affects the wavelength

Linear  dispersion of light

Non-linear dispersion occurs less

Less complicated

Temperature affects the prism

A drive mechanism

 

 

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